Stable Cu and Zn isotope ratios as tracers of sources and transport of Cu and Zn in contaminated soil   总被引：7，自引：0，他引：7  

Moritz Bigalke  Stefan Weyer  Jozef Kobza 《Geochimica et cosmochimica acta》2010,74(23):6801-6813

Copper and Zn metals are produced in large quantities for different applications. During Cu production, large amounts of Cu and Zn can be released to the environment. Therefore, the surroundings of Cu smelters are frequently metal-polluted. We determined Cu and Zn concentrations and Cu and Zn stable isotope ratios (δ⁶⁵Cu, δ⁶⁶Zn) in three soils at distances of 1.1, 3.8, and 5.3 km from a Slovak Cu smelter and in smelter wastes (slag, sludge, ash) to trace sources and transport of Cu and Zn in soils. Stable isotope ratios were measured by multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS) in total digests. Soils were heavily contaminated with concentrations up to 8087 μg g⁻¹ Cu and 2084 μg g⁻¹ Zn in the organic horizons. The δ⁶⁵Cu values varied little (−0.12‰ to 0.36‰) in soils and most wastes and therefore no source identification was possible. In soils, Cu became isotopically lighter with increasing depth down to 0.4 m, likely because of equilibrium reactions between dissolved and adsorbed Cu species during transport of smelter-derived Cu through the soil. The δ⁶⁶Zn_IRMM values were isotopically lighter in ash (−0.41‰) and organic horizons (−0.85‰ to −0.47‰) than in bedrock (−0.28‰) and slag (0.18‰) likely mainly because of kinetic fractionation during evaporation and thus allowed for separation of smelter-Zn from native Zn in soil. In particular in the organic horizons large variations in δ⁶⁶Zn values occur, probably caused by biogeochemical fractionation in the soil-plant system. In the mineral horizons, Zn isotopes showed only minor shifts to heavier δ⁶⁶Zn values with depth mainly because of the mixing of smelter-derived Zn and native Zn in the soils. In contrast to Cu, Zn isotope fractionation between dissolved and adsorbed species was probably only a minor driver in producing the observed variations in δ⁶⁶Zn values. Our results demonstrate that metal stable isotope ratios may serve as tracer of sources, vertical dislocation, and biogeochemical behavior in contaminated soil.  相似文献   

Links Between Bottom-Water Anoxia,the Polychaete <Emphasis Type="Italic">Nereis diversicolor</Emphasis>, and the Growth of Green-Algal Mats     

Anna Engelsen  Kristina Sundbäck  Stefan Hulth 《Estuaries and Coasts》2010,33(6):1365-1376

Sediment–water incubations were used to study effects of episodic anoxia on filamentous Ulva sp. Treatments included undisturbed sediment with (AnoxSed) and without (NatSed) exposure to 5 days of anoxia, and cores with only the top 0.5 cm of sediment (SurfSed; no macrofauna, restricted pore-water nutrient pool). All three treatments contained Ulva propagules. An Ulva mat developed in the SurfSed, and after the anoxic period in the AnoxSed cores. No growth was observed in the NatSed treatment. In the AnoxSed, Ulva was progressively removed upon reoxygenation through grazing by Nereis. The results suggest that episodic anoxia stimulates the growth of macroalgal mats not only by increasing the availability of nutrients from the sediment, but also by reducing macrofaunal grazing pressure. Infauna (grazing and bioturbation), benthic microalgae (nutrient competition and retention), and pore-water nutrients appear key components in a biogeochemical network with complex feedbacks controlling the growth of green-algal mats in shallow-water systems.  相似文献   

A comparison of three Eurasian chironomid–climate calibration datasets on a W–E continentality gradient and the implications for quantitative temperature reconstructions     

Stefan Engels  Angela E. Self  Tomi P. Luoto  Stephen J. Brooks  Karin F. Helmens 《Journal of Paleolimnology》2014,51(4):529-547

Multiple regional chironomid–climate calibration datasets are available to reconstruct quantitatively July air temperatures from fossil chironomid assemblages. We examined the relationship between July air temperature and the 40 most common chironomid taxa in three independent Eurasian calibration (training) sets. The estimated temperature optimum of each chironomid taxon is systematically lower (by ~1–2 °C) in a Norwegian calibration set compared to Finnish and Russian calibration sets. This result might partly be explained by the fact that the Norwegian calibration set extends further at the cold end of the temperature gradient. A difference in continentality between the Russian sites and the European sites might also contribute to this pattern. The number of taxa that show a statistically significant unimodal response to temperature is higher in the Norwegian calibration set (34 out of 40 taxa) compared to the modern Finnish (11 of 37 taxa; 3 common taxa absent) and the Russian calibration set (20 of 40 taxa), probably due to the longer temperature gradient incorporated in the Norwegian calibration set. We applied all three calibration sets to fossil chironomid assemblages from the high-latitude study site of Sokli (northeast Finland), a site with a unique series of lacustrine deposits covering (amongst others) the Holocene, part of early MIS 3 (at ~53 ka) and MIS 5d–c (at ~110–95 ka) and with independent proxy-records for comparison. In the early Holocene and during MIS 5c, the chironomid-based temperature inferences from all three inference models had similar values. Temperature reconstructions based on the Norwegian calibration set are 2–4 °C lower for the late Holocene, early MIS 3 and MIS 5d than the inferred temperatures based on the other calibration sets. Although the lakes included in the Finnish calibration set are located closest to the site of Sokli, evaluation tests and a comparison with independent proxy data suggests that the Norwegian calibration set provides the most suitable analogues for reconstruction purposes for most of the fossil assemblages. Our results imply that when choosing a calibration set for quantitative climate reconstructions on glacial timescales, regional proximity of the fossil site may not be a sufficient basis, and the length of the temperature gradient of the calibration dataset and factors such as the continentality gradient covered by the calibration set must also be considered.  相似文献   

Airborne near-real-time monitoring of assembly and parking areas in case of large-scale public events and natural disasters     

Hannes Römer  Jens Kersten  Ralph Kiefl  Stefan Plattner  Alexander Mager  Stefan Voigt 《International journal of geographical information science》2014,28(4):682-699

A critical requirement for an effective and coordinated response by public entities tasked with management, security, and relief during large-scale public events or natural disasters is the availability of current situational information. However, today there is a lack of comprehensive operational systems allowing a near-real-time (NRT) collection, visualization, and provision of situational information for larger areas. In this study a methodological framework is proposed, which allows an NRT extraction and visualization of situational information based on aerial image acquisition. The framework combines digital image analysis using a generic supervised information extraction approach based on statistical modeling with a downstream web-based visualization component realized through an automatic update of web services. Even though being applicable for different scenarios, the workflow will be demonstrated for the specific use-case of a NRT monitoring of open spaces including assembly and parking areas. Compared to other approaches, image analysis results indicate a high robustness and a low demand for computational power sources (7 seconds per image). Due to a high degree of automation, the proposed workflow contributes to a NRT ‘end-to-end’ monitoring system, which was developed within the VABENE (German acronym for ‘traffic management under large-scale public events and disaster conditions’) project covering all parts from the acquisition of raw aerial imagery to the dissemination of information products to end-users.  相似文献   

The importance of reduced meat and dairy consumption for meeting stringent climate change targets     

Fredrik Hedenus  Stefan Wirsenius  Daniel J. A. Johansson 《Climatic change》2014,124(1-2):79-91

For agriculture, there are three major options for mitigating greenhouse gas (GHG) emissions: 1) productivity improvements, particularly in the livestock sector; 2) dedicated technical mitigation measures; and 3) human dietary changes. The aim of the paper is to estimate long-term agricultural GHG emissions, under different mitigation scenarios, and to relate them to the emissions space compatible with the 2 °C temperature target. Our estimates include emissions up to 2070 from agricultural soils, manure management, enteric fermentation and paddy rice fields, and are based on IPCC Tier 2 methodology. We find that baseline agricultural CO₂-equivalent emissions (using Global Warming Potentials with a 100 year time horizon) will be approximately 13 Gton CO₂eq/year in 2070, compared to 7.1 Gton CO₂eq/year 2000. However, if faster growth in livestock productivity is combined with dedicated technical mitigation measures, emissions may be kept to 7.7 Gton CO₂eq/year in 2070. If structural changes in human diets are included, emissions may be reduced further, to 3–5 Gton CO₂eq/year in 2070. The total annual emissions for meeting the 2 °C target with a chance above 50 % is in the order of 13 Gton CO₂eq/year or less in 2070, for all sectors combined. We conclude that reduced ruminant meat and dairy consumption will be indispensable for reaching the 2 °C target with a high probability, unless unprecedented advances in technology take place.  相似文献   

Multi-proxy summer and winter precipitation reconstruction for southern Africa over the last 200 years     

Raphael Neukom  David J. Nash  Georgina H. Endfield  Stefan W. Grab  Craig A. Grove  Clare Kelso  Coleen H. Vogel  Jens Zinke 《Climate Dynamics》2014,42(9-10):2713-2726

This study presents the first consolidation of palaeoclimate proxy records from multiple archives to develop statistical rainfall reconstructions for southern Africa covering the last two centuries. State-of-the-art ensemble reconstructions reveal multi-decadal rainfall variability in the summer and winter rainfall zones. A decrease in precipitation amount over time is identified in the summer rainfall zone. No significant change in precipitation amount occurred in the winter rainfall zone, but rainfall variability has increased over time. Generally synchronous rainfall fluctuations between the two zones are identified on decadal scales, with common wet (dry) periods reconstructed around 1890 (1930). A strong relationship between seasonal rainfall and sea surface temperatures (SSTs) in the surrounding oceans is confirmed. Coherence among decadal-scale fluctuations of southern African rainfall, regional SST, SSTs in the Pacific Ocean and rainfall in south-eastern Australia suggest SST-rainfall teleconnections across the southern hemisphere. Temporal breakdowns of the SST-rainfall relationship in the southern African regions and the connection between the two rainfall zones are observed, for example during the 1950s. Our results confirm the complex interplay between large-scale teleconnections, regional SSTs and local effects in modulating multi-decadal southern African rainfall variability over long timescales.  相似文献   

Comparison of seismic activity for Llaima and Villarrica volcanoes prior to and after the Maule 2010 earthquake     

Cindy Mora-Stock  Martin Thorwart  Tina Wunderlich  Stefan Bredemeyer  Thor H. Hansteen  Wolfgang Rabbel 《International Journal of Earth Sciences》2014,103(7):2015-2028

Llaima and Villarrica are two of the most active volcanoes in the Chilean Southern Volcanic Zone and presently show contrasting types of activity. Llaima is a closed vent edifice with fumarolic activity, while Villarrica has an open vent with a lava lake, continuous degassing and tremor activity. This study is focused on characterizing the relationships between volcanic and seismic activity in the months before and after the 2010 M8.8 Maule earthquake, which was located in NNW direction from the volcanoes. Time series for tremors, long-period and volcano-tectonic events were obtained from the catalogue of the Volcanic Observatory of the Southern Andes (OVDAS) and from the SFB 574 temporary volcanic network. An increase in the amount of tremor activity, long-period events and degassing rates was observed at Villarrica weeks before the mainshock and continued at a high level also after it. This increase in activity is interpreted to be caused by enhanced magma influx at depth and may be unrelated to the Maule event. In Llaima, an increase in the volcano-tectonic activity was observed directly after the earthquake. The simultaneous post-earthquake activity at both volcanoes is consistent with a structural adjustment response. Since this enhanced activity lasted for more than a year, we suggest that it is related to a medium-term change in the static stress. Thus, the Maule earthquake may have affected both volcanoes, but did not trigger eruptions, from which we assume that none of the volcanoes were in a critical state.  相似文献   

Buried pockmarks on the Top Chalk surface of the Danish North Sea and their potential significance for interpreting palaeocirculation patterns     

Samaneh Masoumi  Lars Reuning  Stefan Back  Alessandro Sandrin  Peter A. Kukla 《International Journal of Earth Sciences》2014,103(2):563-578

Three-dimensional (3D) seismic data from the southern Danish North Sea were used to analyse the morphology and spatial distribution of depressions in the Danian Chalk deposit. Previously, these depressions were either interpreted as karst structures or pockmarks. The observed depressions occur in an interval from 25 ms below to 12 ms above the Top Chalk surface. Three types of depressions were differentiated based on their plan-view geometry and their degree of symmetry: Type 1, comprising sub-circular and symmetrical depressions, is the dominant group (ca. 70 %). Type 2, elongated and symmetrical depressions, represents only a small fraction (ca. 5 %). The elongated and asymmetrical depressions of Type 3 compose ca. 25 %. In cross section, each depression type can be either characterised by a V- or a U-shape. The maximum size of the depressions ranges from 50 to 580 m, with an average internal depth of 10 m. We interpret the depressions as pockmarks formed by the expulsion of biogenic or thermogenic fluids at the Danian seafloor. Likely, the initial form of the pockmarks has been circular (Type 1) and was subsequently modified for Types 2 and 3 to an elongated form by currents. The long axis of the pockmarks is interpreted to represent the effective current direction. The inferred direction is sub-parallel to the palaeobathymetric contours. The 3D seismic interpretation of pockmarks presented in this paper contributes to the understanding of fluid migration and palaeocirculation patterns during the sedimentation of the terminal Chalk Group in the southern Danish North Sea.  相似文献   

Thermophysical properties of Almahata Sitta meteorites (asteroid 2008 TC3) for high‐fidelity entry modeling          下载免费PDF全文

Stefan Loehle  Peter Jenniskens  Hannah Böhrk  Thomas Bauer  Henning Elsäβer  Derek W. Sears  Michael E. Zolensky  Muawia H. Shaddad 《Meteoritics & planetary science》2017,52(2):197-205

Asteroid 2008 TC₃ was characterized in a unique manner prior to impacting Earth's atmosphere, making its October 7, 2008, impact a suitable field test for or validating the application of high‐fidelity re‐entry modeling to asteroid entry. The accurate modeling of the behavior of 2008 TC₃ during its entry in Earth's atmosphere requires detailed information about the thermophysical properties of the asteroid's meteoritic materials at temperatures ranging from room temperature up to the point of ablation (T ~ 1400 K). Here, we present measurements of the thermophysical properties up to these temperatures (in a 1 atm. pressure of argon) for two samples of the Almahata Sitta meteorites from asteroid 2008 TC₃: a thick flat‐faced ureilite suitably shaped for emissivity measurements and a thin flat‐faced EL6 enstatite chondrite suitable for diffusivity measurements. Heat capacity was determined from the elemental composition and density from a 3‐D laser scan of the sample. We find that the thermal conductivity of the enstatite chondrite material decreases more gradually as a function of temperature than expected, while the emissivity of the ureilitic material decreases at a rate of 9.5 × 10^?5 K^?1 above 770 K. The entry scenario is the result of the actual flight path being the boundary to the load the meteorite will be affected with when entering. An accurate heat load prediction depends on the thermophysical properties. Finally, based on these data, the breakup can be calculated accurately leading to a risk assessment for ground damage.  相似文献   

Extreme storms in Malmö, Sweden     

Lars Bengtsson  Stefan Milloti 《水文研究》2010,24(24):3462-3475

  相似文献